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姓 名: | 彭志华 | ||||
职 称: | 副教授 | ||||
导师类别: | 硕士生导师 | ||||
系 室: | 化学系 | ||||
研究领域: | 金属有机化学 | ||||
电子邮箱: | zpech@upc.edu.cn | ||||
联系电话: | 18353268464 | ||||
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◎教育背景 | |||||
1996.9-2000.7,曲阜师范大学化学系,理学学士 2000.9-2003.7,华东师范大学化学系,理学硕士 2008.1-2011.8,德国慕尼黑大学化学系(LMU),博士研究生
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◎工作经历 | |||||
2003.7-2006.3,中国科学院上海有机化学研究所,研究助理 2006.1-2007.1,联合利华上海研发中心,研究助理 2007.3-2007.11,无锡药明康德新药开发有限公司,副高级研究员 2011.10-2020.11,中国石油大学(华东)理学院化学系,讲师 2020.12-2021.12,中国石油大学(华东)理学院化学系,副教授 2022.1-至今,中国石油大学(华东)化学化工学院化学系,副教授
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◎研究方向 | |||||
当前有机化学研究在合成具有生物活性的复杂有机分子,以及高效合成药物分子等方面取得了很大成就。然而,地球上有限的资源和越发严重的环境污染,对有机化学创造新物质提出了更高的要求,即需要寻找更加环境友好,低排放和低消耗,高效、经济和绿色的有机合成化学反应以及简洁高效的多步合成策略。
目前本课题组研究方向包括: [1] 新型有机金属试剂的合成与反应研究 [2] 有机铋参与的基于氧化还原过程的反应研究 [3] 3d金属催化的反应研究 | |||||
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◎科研项目 | |||||
[1] 山东省自然科学基金面上项目(ZR2019MB045) [2] 校自主创新科研计划项目(R1710021A) [3] 国家自然科学青年基金(21202205) [4] 中国博士后科学基金第6批特别资助(2013T60688) [5] 中国博士后科学基金第52批面上二等资助(2012M521382) [6] 山东省自然科学青年基金(ZR2012BQ006) [7] 山东省博士后创新项目专项资金(201203109) [8] 校自主创新科研计划项目(13CX02005A) | |||||
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◎代表性论文及专利 | |||||
1.论文 [1] Direct C-H Arylation and Alkylation of Electron-Deficient Heteroaromatic Compounds with Organozinc Reagents Zhihua Peng,* Chuanman Yu, Yilei Wang, Dongyue Wei, and Cuiyu Jiang Organometallics 2021, 40, 3678–3688. [2] N-Alkylation of Amines with Alcohols Catalyzed by Manganese(II) Chloride or Bromopentacarbonylmanganese(I) Dongyue Wei, Peng Yang, Chuanman Yu, Fengkai Zhao, Yilei Wang, and Zhihua Peng* J. Org. Chem. 2021, 86, 2254−2263. [3] Direct and Efficient C(sp3)‐H Bond Alkylation of Tetrahydroisoquinolines and Isochroman with Alkylzinc Reagents Zhihua Peng*, Yilei Wang, Zhi Yu, Hao Wu, Shanshan Fu, Linhua Song, Cuiyu Jiang Adv. Synth. Catal. 2019, 361, 2048–2053 (VIP). [4] Direct Arylation of Benzyl Ethers with Organozinc Reagents Zhihua Peng*, Yilei Wang, Zhi Yu, Dezhi Zhao, Linhua Song, and Cuiyu Jiang J. Org. Chem. 2018, 83, 7900–7906. [5] Catalytic Regioselective C–H Acetoxylation of Arenes Using 4,6-Dimethoxy-1,3,5-Triazin-2-Yloxy as a Removable/Modifiable Directing Group Zhihua Peng*, Zhi Yu, Tian Li, Na Li, Yilei Wang, Linhua Song, Cuiyu Jiang Organometallics 2017, 36, 2826–2831. [6] Efficient C(Sp3)–H Bond Arylation of Tetrahydroisoquinolines with Knochel-Type Arylzinc Reagents under Oxidative Conditions Zhihua Peng*, Zhi Yu, Dong-Huang Chen, Shuyuan Liang, Liwei Zhang, Dezhi Zhao, Linhua Song, Cuiyu Jiang Synlett 2017, 28, 1835–1839. [7] Highly Diastereoselective Preparation of Aldol Products Using New Functionalized Allylic Aluminum Reagents Zhi-Liang Shen, Zhihua Peng, Chun-Ming Yang, Julian Helberg, Peter Mayer, Ilan Marek, and Paul Knochel* Org. Lett. 2014, 16, 956-959.
[8] The Transition-Metal-Catalyst-Free Oxidative Homocoupling of Organomanganese Reagents Prepared by the Insertion of Magnesium into Organic Halides in the Presence of MnCl2·2LiCl Zhihua Peng,* Na Li, Xinyang Sun, Fang Wang, Lanjian Xu, Cuiyu Jiang, Linhua Song, and Zi-Feng Yan Org. Biomol. Chem. 2014, 12, 7800–7809. [9] Preparation of 2-Magnesiated 1,3,5-Triazines via an Iodine-Magnesium Exchange Zhihua Peng, Benjamin A. Haag, and Paul Knochel* Org. Lett. 2010, 12, 5398-5401 [10] Diastereoselective Synthesis of Homoallylic Alcohols with Adjacent Tertiary and Quaternary Centers by Using Functionalized Allylic Aluminum Reagents Zhihua Peng, Tobias D. Blümke, Peter Mayer, and Paul Knochel* Angew. Chem. Int. Ed. 2010, 49, 8516 –8519. [11] Preparation of Functionalized Organomanganese(II) Reagents by Direct Insertion of Manganese to Aromatic and Benzylic Halides Zhihua Peng, and Paul Knochel* Org. Lett. 2011, 13, 3198-3201. [12] Preparation of Polyfunctional Indazoles and Heteroarylazo Compounds Using Highly Functionalized Zinc Reagents Benjamin Haag, Zhihua Peng, and Paul Knochel* Org. Lett. 2009, 11, 4270-4273. [13] Preparation of functionalized organoaluminiums by direct insertion of aluminium to unsaturated halides Tobias Blümke, Yi-Hung Chen, Zhihua Peng and Paul Knochel* Nature Chemistry, 2010, 2, 313-318. [14] Palladium-Catalyzed Functionalization of Indoles with 2-Acetoxymethyl-Substituted Electron-Deficient Alkenes T Shengming Ma*, Shichao Yu, Zhihua Peng, and Hao Guo J. Org. Chem., 2006, 71, 9865-9868. | |||||
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◎代表性著作 | |||||
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◎获奖情况及荣誉称号 | |||||
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◎执教课程 | |||||
本科生:《有机合成》《波谱分析》《专业外语》《有机化学实验(2-1)》《有机化学实验(2-2)》 研究生:《高等仪器分析》 | |||||
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◎招收及指导研究生情况 | |||||
1.指导研究生情况 独立指导学术研究生3名,协助指导学术研究生3名。 2.招生专业及要求 招收化学专业学术研究生。
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◎学术兼职 | |||||
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